8月10日 美国Baylor University Prof. Zhenrong Zhang学术报告：Molecule-Surface Interactions with TiO2 and MoS2

报告题目: Molecule-Surface Interactions with TiO2 and MoS2 

报告人: Zhenrong Zhang (Associate Professor) 

          Department of Physics, Baylor University, USA 

报告时间： 2017年8月10日 星期四上午10:30 

报告地点： 唐仲英楼 A313 

 

报告内容简介： Interaction of molecules with surfaces of catalysts is critical for understanding catalytic reaction mechanisms. We have studied the interaction of various probe molecules with TiO2 and MoS2 using scanning tunneling microscopy (STM) and tip-enhanced Raman scattering (TERS). Two-dimensional material, MoS2, has attracted tremendous attention due to promising applications in electronics, photonics, and catalysis. Here we compared the difference in the interaction of molecules (H2O, O2, pyridine and thiophene) with monolayer MoS2, bulk MoS2 and Au. The relative Raman peak ratio and Raman peak position shift from spatial TERS mapping show the difference in the adsorbates-adsorbates interaction and the adsorbates-substrates interaction on Au and MoS2 substrates. We have investigated the limits of Raman signal enhancement on MoS2. Employing carboxylic acid, acetone, and formaldehyde as probe molecules, we studied how reactive sites affect the chemical activity of TiO2(110). This unique methodology enables us to achieve the atomic-level understanding of the key elemental reaction steps — adsorption, dissociation, diffusion, and coupling reaction — taking place in heterogeneous catalytic reactions.